Brad Pitt and Angelina Jolie and 14 Famous Celebrity Couples That Began as an Affair

We find love in many ways, and sometimes it happens before we’ve broken things off with a current partner. Even Hollywood isn’t immune to scandalous love affairs. In fact, some of our most iconic celebrity couples fell in love with each other while they were still with other people.

Joanne Woodward and Paul Newman

Joanne Woodward and Paul Newman sitting together in an apartment.

An unexpected romance for them both. | Alan Meek/Daily Express/Hulton Archive/Getty Images

Paul Newman started falling in love with Joanne Woodward the moment he saw her … which happened to be five years before he divorced his first wife, Jackie Witte. Newman eventually got the divorce he sought, and Newman and Woodward enjoyed a 50-year marriage and shared three children together (he had three with Witte as well).

Next: These country crooners had wandering eyes.

Miranda Lambert and Blake Shelton

Miranda Lambert and Blake Shelton hugging in front of a green backdrop.

When these two called it quits they shocked everyone. | Rick Diamond/Getty Images

Although these two both say there was no physical intimacy before his divorce, Blake Shelton admits he fell in love with Miranda Lambert when they first met, which was a year before he separated from his first wife. Lambert and Shelton went on to get married, but they divorced in 2015.

Next: One of the most famous romances in country music history

Johnny Cash and June Carter Cash

June Carter and Johnny Cash performing on stage.

Their lives were all about music and each other. | Scott Harrison/Stringer/Getty Images

Johnny Cash married Vivian Distin in 1954, but he’s best known for his long-standing affair with June Carter. Cash and Carter went on to be married from 1968 until their deaths in 2003.

Next: A Lifetime movie brought these two married actors together.

Leann Rimes and Eddie Cibrian

Eddie Cibrian and LeAnn Rimes standing in front of a pool.

Eddie Cibrian and LeAnn Rimes were one hot couple. | Fabiano Silva/Getty Images for Maxim

Leann Rimes met Eddie Cibrian in 2009, when they filmed a Lifetime movie called Northern Lights. Both were married, Rimes to backup dancer Dean Sheremet, Cibrian to Brandi Glanville. But rumors of an affair soon spread throughout the set, and eventually, Rimes and Cibrian stopped denying the rumors. They divorced their first spouses and got married in 2011.

Next: This Beverly Hills 90210 star left her first husband when she met her current love.

Tori Spelling and Dean McDermott

Tori Spelling and Dean McDermott standing in front of a car.

These two raced to the alter as soon as her divorce was final. | Michael Buckner/Getty Images for Chevrolet Volt

Tori Spelling married Charlie Shanian in 2004, but she soon fell in love with actor Dean McDermott, who was also married. Spelling finalized her divorce in 2006, and she married Dean a month later. The couple now has five children together.

Next: These classic stars carried on a famous affair.

Katharine Hepburn and Spencer Tracy

Spencer Tracy holds Katharine Hepburn in his arms. | Getty Images/Stringer

Katharine Hepburn and Spencer Tracy had a 26-year-long affair despite the fact that he remained married to his wife, Louise. Although Katharine never asked Spencer to divorce his wife and marry her, she stood by his side for decades and was with him when he died in 1967. She did not attend his funeral and only spoke publicly about their relationship after his wife, Louise, passed away.

Next: Even royal status doesn’t make you immune to affairs.

Prince Charles and Camilla Parker Bowles

Prince Charles and his wife Camilla Parker Bowles sitting in chars during an interview.

Married since 2005, Prince Charles and Camilla Parker Bowles attend an event together. | Abdelhak Senna/AFP/Getty Images

Prince Charles was smitten with Camilla as early as 1971, but Palace courtiers claimed she would be an unsuitable wife for the prince. She married Andrew Parker Bowles in 1973, while Prince Charles went on to marry Diana. But Charles and Camilla could never quite stop seeing each other. He and Diana finally divorced in 1996, and he married Camilla in 2005.

Next: This Hollywood affair led to an 18-year marriage.

Melanie Griffith and Antonio Banderas

Melanie Griffith and Antonio Banderes sitting closely together during a dinner.

A very sexy couple to say the least. | Frazer Harrison/iStock/Getty Images

Rumor has it the main reason Antonio Banderas divorced his first wife, Ana Leza, was because he was having an affair with Melanie Griffith. Banderas and Griffith were married for 18 years, but divorced in 2014.

Next: Their 12-year relationship began as an affair.

Angelina Jolie and Brad Pitt

Angelina Jolie and Brad Pitt posing in front of a backdrop on the red carpet.

Perhaps the most iconic power couple of all time. | Kevin Winter/Getty Images

Things heated up for Angelina Jolie and Brad Pitt when they worked together on the set of Mr. and Mrs. Smith in 2004. Pitt was still married to Jennifer Aniston. Although both Jolie and Pitt denied they got physically intimate during that time, they also admitted they fell in love on set. Pitt and Aniston announced their separation in early 2005, and Brangelina began a 12-year romance that only recently ended.

Next: This remains one of Hollywood’s most disturbing tales.

Woody Allen and Soon-Yi Previn

Woody Allen and Soon-Yi Previn standing next to each other at a premiere.

The public views their relationship as highly controversial. | Jamie McCarthy/Getty Images

Woody Allen’s longtime girlfriend Mia Farrow discovered he was having an affair with her 19-year-old adopted daughter, Soon-Yi when she found lewd photos of Soon-Yi in Allen’s apartment. Allen and Previn have been married since 1997, despite a 35-year age difference.

Next: This romance turned out to be “toxic.”

Britney Spears and Kevin Federline

Britney Spears and Kevin Federline walking while holding hands.

This relationship will go down in pop culture history | Vince Bucci/Getty Images

This couple made headlines in 2004 when Kevin Federline left his fiance, Shar Jacskon, for Britney Spears while Shar was pregnant with their second child. Spears and Federline were married for three years and had two sons together before she filed for divorce in 2007.

Next: We call it karma, Crudup.

Claire Danes and Hugh Dancy

Claire Danes and Hugh Dancy attend a red carpet event together.

Claire Danes took a while in finding her perfect match. | Dia Dipasupil/Getty Images For Entertainment Weekly

In 2003, actor Billy Crudup left his girlfriend, Mary Louise Parker, when she was seven months pregnant in order to pursue a relationship with Claire Danes. Crudup and Danes dated for four years, but Danes ended up leaving him for Hugh Dancy, whom she later married.

Next: This Hollywood duo married twice.

Elizabeth Taylor and Richard Burton

Elizabeth Taylor looks at Richard Burton.

They attempted a fairy tale ending twice. | William Lovelace/Getty Images

Elizabeth Taylor was married eight times, but Richard Burton is the only man she married twice. The two began a passionate affair while on the set of Cleopatra in 1962, when both of them were married to other people. They left their spouses and wed in 1964. They divorced in 1974 and remarried a year later, but the second marriage didn’t even last a year.

Next: Another love triangle for Elizabeth.

Elizabeth Taylor and Eddie Fisher

Elizabeth Taylor and Eddie Fisher look at each other happily.

A very trick relationship. | Keystone/Getty Images

Before there was Richard Burton, there was Eddie Fisher, the husband of actress Debbie Reynolds. Fisher and Reynolds were close to Taylor and her husband, Mike Todd. But when Todd was killed in a plane crash in 1958, Taylor leaned on her friends for support … and she and Fisher fell in love. Fisher left his wife for Taylor, but obviously, the love didn’t last.

Next: Pretty woman, ugly start

Julia Roberts and Danny Moder

Julia Roberts looking at Danny Moder while they speak on stage.

Julia Roberts met her husband on set. | Frederick M. Brown/Getty Images

When Julia Roberts met husband Danny Moder on the set of The Mexican in 2001, she was dating Benjamin Bratt and Moder was married to Vera Steimberg. He eventually left Steimberg for Roberts, but when Steimberg didn’t initially agree to the terms of the divorce, Roberts wore an “A Low, Vera” shirt in public. Ouch. For what it’s worth, Julia Roberts says she has remorse over the affair.

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